TY - JOUR
T1 - Zinc(II) complexes of 4-aminoantipyrine (AAP). Crystal structure of [Zn(AAP)2Cl2]
AU - Faraz, Muhammad Muhsin
AU - Isab, Anvarhusein A.
AU - Alotaibi, Mshari A.
AU - Alharthi, Abdulrahman I.
AU - Tahir, Muhammad Nawaz
AU - Monim-ul-Mehboob, Muhammad
AU - Ahmad, Saeed
N1 - Publisher Copyright:
© 2017, Pleiades Publishing, Ltd.
PY - 2017/7/1
Y1 - 2017/7/1
N2 - Zinc(II) complexes of 4-aminoantipyrine (AAP), [Zn(AAP)2X2] (X = Cl–, I–) and [Zn(AAP)(CN)2] · 2H2O were prepared and characterized by elemental analysis, IR and NMR (1H & 13C) spectroscopy. The crystal structure of [Zn(AAP)2Cl2] (1) was determined by X-ray crystallography. The structural analysis of 1 shows that the complex exists as a monomeric nonionic molecule with zinc atom bound to two AAP ligands and two chloride ions adopting a distorted tetrahedral geometry. In [Zn(AAP)2(CN)2] · 2H2O, the appearance of a band at 2162 cm–1 in IR and resonances around 142 ppm in the 13C NMR spectra indicated the binding of cyanide to zinc(II).
AB - Zinc(II) complexes of 4-aminoantipyrine (AAP), [Zn(AAP)2X2] (X = Cl–, I–) and [Zn(AAP)(CN)2] · 2H2O were prepared and characterized by elemental analysis, IR and NMR (1H & 13C) spectroscopy. The crystal structure of [Zn(AAP)2Cl2] (1) was determined by X-ray crystallography. The structural analysis of 1 shows that the complex exists as a monomeric nonionic molecule with zinc atom bound to two AAP ligands and two chloride ions adopting a distorted tetrahedral geometry. In [Zn(AAP)2(CN)2] · 2H2O, the appearance of a band at 2162 cm–1 in IR and resonances around 142 ppm in the 13C NMR spectra indicated the binding of cyanide to zinc(II).
UR - http://www.scopus.com/inward/record.url?scp=85026805247&partnerID=8YFLogxK
U2 - 10.1134/S0036023617070075
DO - 10.1134/S0036023617070075
M3 - Article
AN - SCOPUS:85026805247
SN - 0036-0236
VL - 62
SP - 925
EP - 930
JO - Russian Journal of Inorganic Chemistry
JF - Russian Journal of Inorganic Chemistry
IS - 7
ER -