Synthesis, growth, and characterisation of a novel organic–inorganic perovskite-type hybrid system based on glycine

A. Kaiba; Mohammed H. Geesi; P. Guionneau; Yassine Riadi; Talal A. Aljohani; Ammar Elfatih Elsanousi; Oussama Ouerghi

doi:10.1016/j.molstruc.2020.129008

Synthesis, growth, and characterisation of a novel organic–inorganic perovskite-type hybrid system based on glycine

A. Kaiba, Mohammed H. Geesi, P. Guionneau, Yassine Riadi, Talal A. Aljohani, Ammar Elfatih Elsanousi, Oussama Ouerghi

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A new organic–inorganic hybrid with the empirical formula [NH₃[sbnd]CH₂[sbnd]COOH]CdCl₃.H₂O has been crystallised, and the structure was solved at room temperature (system (orthorhombic), space group (Pcam), unit parameters cell (a = 7.433(10) Å, b = 7.743(2) Å, c = 25.346(6) Å), volume 1458.76 (5) Å³), Z = 8). The asymmetric unit cell consists of a combination of [Cd _0.5 Cl₃]^– anions, one organic ⁺NH₃(CH₂)CO₂H cations, and one water molecule to form a two-dimensional perovskite system. The hydrogen-bonding network ensures cohesion between these layers. The micro-Raman spectroscopy measurement technique is used to probe organic−inorganic halide perovskite vibration modes. The compound was, also, characterised using the vibrating sample magnetometer VSM and the UV–visible absorption techniques.

Original language	English
Article number	129008
Journal	Journal of Molecular Structure
Volume	1224
DOIs	https://doi.org/10.1016/j.molstruc.2020.129008
State	Published - 15 Jan 2021

Keywords

Crystal structure
Micro-raman spectroscopy
Organic–inorganic hybrid
Vibrating sample magnetometer
X-ray diffraction

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@article{ae5e3dad4303494390538c6b99fae523,

title = "Synthesis, growth, and characterisation of a novel organic–inorganic perovskite-type hybrid system based on glycine",

abstract = "A new organic–inorganic hybrid with the empirical formula [NH3[sbnd]CH2[sbnd]COOH]CdCl3.H2O has been crystallised, and the structure was solved at room temperature (system (orthorhombic), space group (Pcam), unit parameters cell (a = 7.433(10) {\AA}, b = 7.743(2) {\AA}, c = 25.346(6) {\AA}), volume 1458.76 (5) {\AA}3), Z = 8). The asymmetric unit cell consists of a combination of [Cd 0.5 Cl3]– anions, one organic +NH3(CH2)CO2H cations, and one water molecule to form a two-dimensional perovskite system. The hydrogen-bonding network ensures cohesion between these layers. The micro-Raman spectroscopy measurement technique is used to probe organic−inorganic halide perovskite vibration modes. The compound was, also, characterised using the vibrating sample magnetometer VSM and the UV–visible absorption techniques.",

keywords = "Crystal structure, Micro-raman spectroscopy, Organic–inorganic hybrid, Vibrating sample magnetometer, X-ray diffraction",

author = "A. Kaiba and Geesi, \{Mohammed H.\} and P. Guionneau and Yassine Riadi and Aljohani, \{Talal A.\} and \{Elfatih Elsanousi\}, Ammar and Oussama Ouerghi",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2021",

month = jan,

day = "15",

doi = "10.1016/j.molstruc.2020.129008",

language = "English",

volume = "1224",

journal = "Journal of Molecular Structure",

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T1 - Synthesis, growth, and characterisation of a novel organic–inorganic perovskite-type hybrid system based on glycine

AU - Kaiba, A.

AU - Geesi, Mohammed H.

AU - Guionneau, P.

AU - Riadi, Yassine

AU - Aljohani, Talal A.

AU - Elfatih Elsanousi, Ammar

AU - Ouerghi, Oussama

PY - 2021/1/15

Y1 - 2021/1/15

N2 - A new organic–inorganic hybrid with the empirical formula [NH3[sbnd]CH2[sbnd]COOH]CdCl3.H2O has been crystallised, and the structure was solved at room temperature (system (orthorhombic), space group (Pcam), unit parameters cell (a = 7.433(10) Å, b = 7.743(2) Å, c = 25.346(6) Å), volume 1458.76 (5) Å3), Z = 8). The asymmetric unit cell consists of a combination of [Cd 0.5 Cl3]– anions, one organic +NH3(CH2)CO2H cations, and one water molecule to form a two-dimensional perovskite system. The hydrogen-bonding network ensures cohesion between these layers. The micro-Raman spectroscopy measurement technique is used to probe organic−inorganic halide perovskite vibration modes. The compound was, also, characterised using the vibrating sample magnetometer VSM and the UV–visible absorption techniques.

AB - A new organic–inorganic hybrid with the empirical formula [NH3[sbnd]CH2[sbnd]COOH]CdCl3.H2O has been crystallised, and the structure was solved at room temperature (system (orthorhombic), space group (Pcam), unit parameters cell (a = 7.433(10) Å, b = 7.743(2) Å, c = 25.346(6) Å), volume 1458.76 (5) Å3), Z = 8). The asymmetric unit cell consists of a combination of [Cd 0.5 Cl3]– anions, one organic +NH3(CH2)CO2H cations, and one water molecule to form a two-dimensional perovskite system. The hydrogen-bonding network ensures cohesion between these layers. The micro-Raman spectroscopy measurement technique is used to probe organic−inorganic halide perovskite vibration modes. The compound was, also, characterised using the vibrating sample magnetometer VSM and the UV–visible absorption techniques.

KW - Crystal structure

KW - Micro-raman spectroscopy

KW - Organic–inorganic hybrid

KW - Vibrating sample magnetometer

KW - X-ray diffraction

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U2 - 10.1016/j.molstruc.2020.129008

DO - 10.1016/j.molstruc.2020.129008

M3 - Article

AN - SCOPUS:85089138004

SN - 0022-2860

VL - 1224

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

M1 - 129008

ER -

Synthesis, growth, and characterisation of a novel organic–inorganic perovskite-type hybrid system based on glycine

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