TY - JOUR
T1 - Synthesis, Characterization of CoFe2O4 and CoAl0.8Fe2O4
T2 - A Novel Catalyst for the Synthesis of 12-Aryl/Hetroaryl-8,9,10,12-Tetrahydrobenzo[a]Xanthen-11-Ones Derivatives in Semi-Aqueous Condition
AU - Alotaibi, Mshari
AU - Bakht, Md Afroz
AU - Alharthi, Abdulrahman A.
N1 - Publisher Copyright:
© 2022 Taylor & Francis Group, LLC.
PY - 2023
Y1 - 2023
N2 - The current research focuses on the utilization of cobalt ferrite and Al-doped cobalt ferrite as catalysts for the synthesis of 12-aryl/heteroaryl-8,9,10,12-tetrahydrobenzo[a]xanthene-11-ones derivatives in semi-aqueous conditions. Doping some aluminum metal into CoFe2O4 improved its catalytic potential, which was then utilized in chemical synthesis. The produced catalyst was recycled in numerous reactions to test its stability. Characterization of the catalysts was done using FT-IR, XRD, BET, and SEM techniques. The grade of the catalysts was also determined by the yield of xanthene derivatives. The effect of pure cobalt ferrite and varied molar ratios of aluminum cobalt ferrite on the yield and reaction time of xanthene derivatives has been thoroughly explored. Xanthene derivatives having aryl moiety showed better results in terms of reaction times and yield as compared to heteroaryl. Cost-effective, recyclable catalysts producing excellent yield in short reaction time, with easy work method are some salient features of current research.
AB - The current research focuses on the utilization of cobalt ferrite and Al-doped cobalt ferrite as catalysts for the synthesis of 12-aryl/heteroaryl-8,9,10,12-tetrahydrobenzo[a]xanthene-11-ones derivatives in semi-aqueous conditions. Doping some aluminum metal into CoFe2O4 improved its catalytic potential, which was then utilized in chemical synthesis. The produced catalyst was recycled in numerous reactions to test its stability. Characterization of the catalysts was done using FT-IR, XRD, BET, and SEM techniques. The grade of the catalysts was also determined by the yield of xanthene derivatives. The effect of pure cobalt ferrite and varied molar ratios of aluminum cobalt ferrite on the yield and reaction time of xanthene derivatives has been thoroughly explored. Xanthene derivatives having aryl moiety showed better results in terms of reaction times and yield as compared to heteroaryl. Cost-effective, recyclable catalysts producing excellent yield in short reaction time, with easy work method are some salient features of current research.
KW - CoAlFeO
KW - CoFeO
KW - semi-aqueous
KW - xanthene
UR - http://www.scopus.com/inward/record.url?scp=85132633658&partnerID=8YFLogxK
U2 - 10.1080/10406638.2022.2072910
DO - 10.1080/10406638.2022.2072910
M3 - Article
AN - SCOPUS:85132633658
SN - 1040-6638
VL - 43
SP - 3522
EP - 3534
JO - Polycyclic Aromatic Compounds
JF - Polycyclic Aromatic Compounds
IS - 4
ER -