Synthesis, antimicrobial evaluation, crystal structure, Hirschfeld surface analysis and docking studies of 4-[2-(1-methyl-1H-imidazol-2-ylsulfanyl)-acetylamino]-benzenesulfonic acid

Mohammed H. Geesi, Yassine Riadi, Abdellah Kaiba, Elmutasim O. Ibnouf, El Hassane Anouar, Oussama Dehbi, Saïd Lazar, Philippe Guionneau

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

The synthesis of a new 4-[2-(1-methyl-1H-imidazol-2-ylsulfanyl)-acetylamino]-benzenesulfonic acid from available reagents using an efficient strategy was reported, and its antimicrobial ability against bacterial strains was investigated. This new compound was characterised using a single crystal technique, which showed that the compound crystallised with a monoclinic system in a P21/c space group. Its unit-cell parameters were a = 17.0692 (2) Å, b = 5.0326 (3) Å, c = 17.2979 (4) Å, β = 106.596° (2) and Z = 4. Crystal packing was stabilised by hydrogen bonds, pi- stacking, C–H….pi and van der Waals interactions. The intermolecular interaction analysis of the crystal structure was affected by Hirschfeld surface analysis, and associated two-dimensional fingerprint plots were utilised. In addition, docking investigations of the biological activity of the synthesised compound was also performed.

Original languageEnglish
Article number133425
JournalJournal of Molecular Structure
Volume1265
DOIs
StatePublished - 5 Oct 2022

Keywords

  • Antimicrobial activity, Docking
  • Crystal structure
  • Hirshfeld surface analysis
  • Synthesis

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