TY - JOUR
T1 - Synthesis and characterization of efficient Sr-doped ZnO nanostructures for optoelectronic, and photocatalytic applications
AU - Saeeda Javaid, Alqa
AU - Saeeda Javaid, Wajeeha
AU - Adnan, Muhammad
AU - Usman, Muhammad
AU - Aftab Akram, Muhammad
AU - Bashir, Najma
AU - Khalid, Awais
AU - Fazale Ahmad, Pervaiz
AU - Hossin, Mousa M.
AU - Liaqat, Iram
AU - Ismail, Mohamed A.
AU - Dib, Hanna
AU - Arshad, Natasha
N1 - Publisher Copyright:
© 2024 Elsevier B.V.
PY - 2024/4
Y1 - 2024/4
N2 - With increasing technological advancements, optoelectronics emergence is inevitable. Various metal oxides are explored for optoelectronics properties and Zinc oxide-based nanostructures have various advantages that can be explored in optoelectronic devices. Nanomaterials that are undoped and Strontium doped were synthesized via a simple wet chemistry route. The study set out to quantify the impact of Strontium doping in Zinc Oxide on optical and photocatalytic properties. The doping of strontium concentration within ZnO varied from 0 % to 3 % by weight of the total molar ratio. The characterization of SZO nanomaterials was done using measurements of X-ray diffraction, Raman Spectroscopy, SEM, Hall effect measurements, UV/Vis, and PL regarding their structural properties, morphological properties, optical properties, and electrical characteristics. X-ray diffraction analysis showed that the Sr-doped ZnO had the hexagonal wurtzite structure of zinc oxide. SEM showed that the morphology of Sr-doped ZnO thin films changed by increasing Sr concentration. Meanwhile, the film's surface was smooth and crack-free. In UV–Vis experiments, the concentration of Sr doping reduced the optical band gap ranges from 3.27 eV to 2.98 eV. All the samples exhibited n-type conductivity in the Hall Effect. Photocatalytic degradation Methylene Blue was studied and SZO (3 at. %) was best for degradation with efficiency over 80 %.
AB - With increasing technological advancements, optoelectronics emergence is inevitable. Various metal oxides are explored for optoelectronics properties and Zinc oxide-based nanostructures have various advantages that can be explored in optoelectronic devices. Nanomaterials that are undoped and Strontium doped were synthesized via a simple wet chemistry route. The study set out to quantify the impact of Strontium doping in Zinc Oxide on optical and photocatalytic properties. The doping of strontium concentration within ZnO varied from 0 % to 3 % by weight of the total molar ratio. The characterization of SZO nanomaterials was done using measurements of X-ray diffraction, Raman Spectroscopy, SEM, Hall effect measurements, UV/Vis, and PL regarding their structural properties, morphological properties, optical properties, and electrical characteristics. X-ray diffraction analysis showed that the Sr-doped ZnO had the hexagonal wurtzite structure of zinc oxide. SEM showed that the morphology of Sr-doped ZnO thin films changed by increasing Sr concentration. Meanwhile, the film's surface was smooth and crack-free. In UV–Vis experiments, the concentration of Sr doping reduced the optical band gap ranges from 3.27 eV to 2.98 eV. All the samples exhibited n-type conductivity in the Hall Effect. Photocatalytic degradation Methylene Blue was studied and SZO (3 at. %) was best for degradation with efficiency over 80 %.
KW - Optical properties
KW - Optoelectronics
KW - Photocatalysis
KW - Photoluminescence
KW - Sr doped ZnO
KW - ZnO
UR - http://www.scopus.com/inward/record.url?scp=85186502609&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2024.112175
DO - 10.1016/j.inoche.2024.112175
M3 - Article
AN - SCOPUS:85186502609
SN - 1387-7003
VL - 162
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
M1 - 112175
ER -