TY - JOUR
T1 - Preparation of PVDF-co-PAAm membrane with robust antifouling, and antibacterial performance by blending with magnetic graphene oxide
AU - Aldawsari, Abdullah M.
AU - Hassan, Hassan M.A.
AU - Alrashidi, Abdulelah Nashmi
AU - Alsohaimi, Ibrahim Hotan
AU - Moustafa, Shaima M.N.
AU - Youssef, Hany M.
AU - Hamdi, Raghda
AU - Azzam, Maged A.
N1 - Publisher Copyright:
© 2022 Elsevier Ltd.
PY - 2022/6
Y1 - 2022/6
N2 - Ultrafiltration membranes (UF) have been utilized in a variety of industrial sectors. However, the primary challenge with UF membrane is fouling. To prevent this problem, the PVDF-co-PAAm copolymer blended with magnetic graphene oxide (MGO) was prepared using a nonsolvent induced phase separation (NIPS) approach to develop the PVDF-co-PAAm /MGO nanocomposite membrane. As a comparison, the efficiency of the membranes was assessed using four types of PVDF, PVDF-co-PAAm, PVDF-co-PAAm /GO, and PVDF-co-PAAm /MGO. The chemical structure and morphology were characterized by ATR-FTIR, XRD, FESEM, ζ-potential, and hydrophilicity. The assessment of the synthesized membranes performance was comprised permeation, antifouling, and antibacterial activities. The ATR-FTIR spectra and XRD pattern confirmed that PVDF-co-PAAm/MGO was successfully prepared. FESEM assessment confirm that the PVDF-co-PAAm/MGO membrane illustrated the ultrafiltration morphology. Membrane hydrophilicity and porous homogeneity were both boosted. A 60% improve in pure water flux, 110% improve in flux recovery ratio, and 125% improve in rejection % were attained when PVDF-co-PAAm was blended with MGO. The Rr may rise from 6.05% to 39.81%, while the Rir may decline from 53.53% to 42.16%. Additionally, the amended membrane demonstrated strong antibacterial activity, with a maximum antibacterial ratio. In conclusion, the blending of PVDF-co-PAAm with MGO might result in membranes with a robust hydrophilicity, water flux, rejection (%) and antibacterial activities.
AB - Ultrafiltration membranes (UF) have been utilized in a variety of industrial sectors. However, the primary challenge with UF membrane is fouling. To prevent this problem, the PVDF-co-PAAm copolymer blended with magnetic graphene oxide (MGO) was prepared using a nonsolvent induced phase separation (NIPS) approach to develop the PVDF-co-PAAm /MGO nanocomposite membrane. As a comparison, the efficiency of the membranes was assessed using four types of PVDF, PVDF-co-PAAm, PVDF-co-PAAm /GO, and PVDF-co-PAAm /MGO. The chemical structure and morphology were characterized by ATR-FTIR, XRD, FESEM, ζ-potential, and hydrophilicity. The assessment of the synthesized membranes performance was comprised permeation, antifouling, and antibacterial activities. The ATR-FTIR spectra and XRD pattern confirmed that PVDF-co-PAAm/MGO was successfully prepared. FESEM assessment confirm that the PVDF-co-PAAm/MGO membrane illustrated the ultrafiltration morphology. Membrane hydrophilicity and porous homogeneity were both boosted. A 60% improve in pure water flux, 110% improve in flux recovery ratio, and 125% improve in rejection % were attained when PVDF-co-PAAm was blended with MGO. The Rr may rise from 6.05% to 39.81%, while the Rir may decline from 53.53% to 42.16%. Additionally, the amended membrane demonstrated strong antibacterial activity, with a maximum antibacterial ratio. In conclusion, the blending of PVDF-co-PAAm with MGO might result in membranes with a robust hydrophilicity, water flux, rejection (%) and antibacterial activities.
KW - Antibacterial
KW - Antifouling performance
KW - Graphene oxide
KW - Hydrophilicity
KW - PVDF
UR - http://www.scopus.com/inward/record.url?scp=85132693339&partnerID=8YFLogxK
U2 - 10.1016/j.jece.2022.108093
DO - 10.1016/j.jece.2022.108093
M3 - Article
AN - SCOPUS:85132693339
SN - 2213-2929
VL - 10
JO - Journal of Environmental Chemical Engineering
JF - Journal of Environmental Chemical Engineering
IS - 3
M1 - 108093
ER -