Preparation of PVDF-co-PAAm membrane with robust antifouling, and antibacterial performance by blending with magnetic graphene oxide

Abdullah M. Aldawsari, Hassan M.A. Hassan, Abdulelah Nashmi Alrashidi, Ibrahim Hotan Alsohaimi, Shaima M.N. Moustafa, Hany M. Youssef, Raghda Hamdi, Maged A. Azzam

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18 Scopus citations

Abstract

Ultrafiltration membranes (UF) have been utilized in a variety of industrial sectors. However, the primary challenge with UF membrane is fouling. To prevent this problem, the PVDF-co-PAAm copolymer blended with magnetic graphene oxide (MGO) was prepared using a nonsolvent induced phase separation (NIPS) approach to develop the PVDF-co-PAAm /MGO nanocomposite membrane. As a comparison, the efficiency of the membranes was assessed using four types of PVDF, PVDF-co-PAAm, PVDF-co-PAAm /GO, and PVDF-co-PAAm /MGO. The chemical structure and morphology were characterized by ATR-FTIR, XRD, FESEM, ζ-potential, and hydrophilicity. The assessment of the synthesized membranes performance was comprised permeation, antifouling, and antibacterial activities. The ATR-FTIR spectra and XRD pattern confirmed that PVDF-co-PAAm/MGO was successfully prepared. FESEM assessment confirm that the PVDF-co-PAAm/MGO membrane illustrated the ultrafiltration morphology. Membrane hydrophilicity and porous homogeneity were both boosted. A 60% improve in pure water flux, 110% improve in flux recovery ratio, and 125% improve in rejection % were attained when PVDF-co-PAAm was blended with MGO. The Rr may rise from 6.05% to 39.81%, while the Rir may decline from 53.53% to 42.16%. Additionally, the amended membrane demonstrated strong antibacterial activity, with a maximum antibacterial ratio. In conclusion, the blending of PVDF-co-PAAm with MGO might result in membranes with a robust hydrophilicity, water flux, rejection (%) and antibacterial activities.

Original languageEnglish
Article number108093
JournalJournal of Environmental Chemical Engineering
Volume10
Issue number3
DOIs
StatePublished - Jun 2022

Keywords

  • Antibacterial
  • Antifouling performance
  • Graphene oxide
  • Hydrophilicity
  • PVDF

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