Piezoelectric and ferroelectric properties of lead-free Ga-modified 0.65BiFeO3–0.35BaTiO3 ceramics by water quenching process

Salman Ali Khan; Fazli Akram; Rizwan Ahmed Malik; Jun Chan Kim; Riffat Asim Pasha; Soonil Lee; Tae Kwon Song; Yeon Soo Sung; M. H. Kim

doi:10.1080/00150193.2019.1574642

Piezoelectric and ferroelectric properties of lead-free Ga-modified 0.65BiFeO₃–0.35BaTiO₃ ceramics by water quenching process

Salman Ali Khan, Fazli Akram, Rizwan Ahmed Malik, Jun Chan Kim, Riffat Asim Pasha, Soonil Lee, Tae Kwon Song, Yeon Soo Sung, M. H. Kim

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Binary solid solution of gallium (Ga³⁺)-modified 0.65Bi_1.05FeO₃–0.35BaTiO₃ (BFGO–BTO with 0–2 mol% Ga³⁺ content) ceramics were synthesized by a solid-state reaction method, followed by water quenching process. The effects of Ga³⁺ modifications on the crystal structure, microstructure, dielectric, ferroelectric, and piezoelectric properties of the BFO–BTO ceramics were studied. X-ray diffraction patterns confirmed a single perovskite phase without any secondary phases. Improvements of ferroelectric and piezoelectric properties were obtained at the optimum composition of BFGO–BTO system. Meanwhile, BFGO–BTO ceramics had a high static piezoelectric coefficient (d₃₃) of 128 pC/N at 1.5 mol% Ga³⁺-content with relatively high operating temperature compared to other lead-free bismuth (Bi)-based systems.

Original language	English
Pages (from-to)	54-60
Number of pages	7
Journal	Ferroelectrics
Volume	541
Issue number	1
DOIs	https://doi.org/10.1080/00150193.2019.1574642
State	Published - 12 Mar 2019
Externally published	Yes

Keywords

BFGO–BTO
dielectric
ferroelectric properties
Lead-free piezoelectric

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10.1080/00150193.2019.1574642

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@article{7066997cabad49e2960f8815e747edad,

title = "Piezoelectric and ferroelectric properties of lead-free Ga-modified 0.65BiFeO3–0.35BaTiO3 ceramics by water quenching process",

abstract = "Binary solid solution of gallium (Ga3+)-modified 0.65Bi1.05FeO3–0.35BaTiO3 (BFGO–BTO with 0–2 mol\% Ga3+ content) ceramics were synthesized by a solid-state reaction method, followed by water quenching process. The effects of Ga3+ modifications on the crystal structure, microstructure, dielectric, ferroelectric, and piezoelectric properties of the BFO–BTO ceramics were studied. X-ray diffraction patterns confirmed a single perovskite phase without any secondary phases. Improvements of ferroelectric and piezoelectric properties were obtained at the optimum composition of BFGO–BTO system. Meanwhile, BFGO–BTO ceramics had a high static piezoelectric coefficient (d33) of 128 pC/N at 1.5 mol\% Ga3+-content with relatively high operating temperature compared to other lead-free bismuth (Bi)-based systems.",

keywords = "BFGO–BTO, dielectric, ferroelectric properties, Lead-free piezoelectric",

author = "Khan, \{Salman Ali\} and Fazli Akram and Malik, \{Rizwan Ahmed\} and Kim, \{Jun Chan\} and Pasha, \{Riffat Asim\} and Soonil Lee and Song, \{Tae Kwon\} and Sung, \{Yeon Soo\} and Kim, \{M. H.\}",

note = "Publisher Copyright: {\textcopyright} 2019, {\textcopyright} 2019 Taylor \& Francis Group, LLC.",

year = "2019",

month = mar,

day = "12",

doi = "10.1080/00150193.2019.1574642",

language = "English",

volume = "541",

pages = "54--60",

journal = "Ferroelectrics",

issn = "0015-0193",

publisher = "Taylor and Francis Ltd.",

number = "1",

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TY - JOUR

T1 - Piezoelectric and ferroelectric properties of lead-free Ga-modified 0.65BiFeO3–0.35BaTiO3 ceramics by water quenching process

AU - Khan, Salman Ali

AU - Akram, Fazli

AU - Malik, Rizwan Ahmed

AU - Kim, Jun Chan

AU - Pasha, Riffat Asim

AU - Lee, Soonil

AU - Song, Tae Kwon

AU - Sung, Yeon Soo

AU - Kim, M. H.

PY - 2019/3/12

Y1 - 2019/3/12

N2 - Binary solid solution of gallium (Ga3+)-modified 0.65Bi1.05FeO3–0.35BaTiO3 (BFGO–BTO with 0–2 mol% Ga3+ content) ceramics were synthesized by a solid-state reaction method, followed by water quenching process. The effects of Ga3+ modifications on the crystal structure, microstructure, dielectric, ferroelectric, and piezoelectric properties of the BFO–BTO ceramics were studied. X-ray diffraction patterns confirmed a single perovskite phase without any secondary phases. Improvements of ferroelectric and piezoelectric properties were obtained at the optimum composition of BFGO–BTO system. Meanwhile, BFGO–BTO ceramics had a high static piezoelectric coefficient (d33) of 128 pC/N at 1.5 mol% Ga3+-content with relatively high operating temperature compared to other lead-free bismuth (Bi)-based systems.

AB - Binary solid solution of gallium (Ga3+)-modified 0.65Bi1.05FeO3–0.35BaTiO3 (BFGO–BTO with 0–2 mol% Ga3+ content) ceramics were synthesized by a solid-state reaction method, followed by water quenching process. The effects of Ga3+ modifications on the crystal structure, microstructure, dielectric, ferroelectric, and piezoelectric properties of the BFO–BTO ceramics were studied. X-ray diffraction patterns confirmed a single perovskite phase without any secondary phases. Improvements of ferroelectric and piezoelectric properties were obtained at the optimum composition of BFGO–BTO system. Meanwhile, BFGO–BTO ceramics had a high static piezoelectric coefficient (d33) of 128 pC/N at 1.5 mol% Ga3+-content with relatively high operating temperature compared to other lead-free bismuth (Bi)-based systems.

KW - BFGO–BTO

KW - dielectric

KW - ferroelectric properties

KW - Lead-free piezoelectric

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U2 - 10.1080/00150193.2019.1574642

DO - 10.1080/00150193.2019.1574642

M3 - Article

AN - SCOPUS:85068769453

SN - 0015-0193

VL - 541

SP - 54

EP - 60

JO - Ferroelectrics

JF - Ferroelectrics

IS - 1

ER -

Piezoelectric and ferroelectric properties of lead-free Ga-modified 0.65BiFeO₃–0.35BaTiO₃ ceramics by water quenching process

Abstract

Keywords

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