Micromechanical modeling of thermal conductivities of unidirectional carbon fiber/epoxy composites containing carbon nanotube/graphene hybrids

This article deals with the micromechanical modeling of thermal conductivities of the unidirectional carbon fiber (CF)-reinforced composites with carbon nanotube (CNT)/graphene nanoplatelet (GNP)-enriched epoxy matrix. The thermal conductivity of epoxy-based nanocompounds enriched through the incorporation of CNT/GNP hybrids is estimated within the framework of micromechanics. The significant contribution of several microstructures, including the volume fraction, dimension, and straightness of nanofillers, thermal resistance at the interface of the nanofillers and epoxy matrix, and the percolation effect on the nanocomposite thermal conductivity is considered. Furthermore, the method of cells (MOC) is used to anticipate the axial and transverse thermal conductances of unidirectional composites featuring CFs integrated into the CNT/GNP-enriched polymer nanocomposite matrix. The results reveal that incorporating a combination of GNTs and CNTs into the polymer matrix significantly increases the transverse thermal conduction of the multiphase compound. Several factors contribute to improved thermal conductance of the transverse direction in CF/CNT/GNP composites: (i) higher nanofiller concentration, (ii) presence of straight nanofillers, and (iii) use of larger nanofillers. The predictions of micromechanical modeling give good agreement with available experiments. This study compares the transverse and axial thermal conductivity of unidirectional compounds predicted by MOC method with results obtained using the finite element method.