TY - JOUR
T1 - Facile Fabrication of a Free-Standing Magnesium Oxide-Graphene Oxide Functionalized Membrane
T2 - A Robust and Efficient Material for the Removal of Pollutants from Aqueous Matrices
AU - Khilji, Meher Un Nisa
AU - Otho, Aijaz Ali
AU - Memon, Roomia
AU - Khalid, Awais
AU - Kazi, Mohsin
AU - Hyder, Ali
AU - Janwery, Dahar
AU - Nahyoon, Noor Ahmed
AU - Memon, Ayaz Ali
AU - Memon, Najma
AU - Thebo, Khalid Hussain
N1 - Publisher Copyright:
© 2023 Taylor & Francis Group, LLC.
PY - 2024
Y1 - 2024
N2 - Environmental pollution significantly challenges human health, ecosystems, and the planet’s sustainability. Widespread air, water, and soil contamination from various pollutants requires effective and sustainable solutions to reduce or eliminate pollution and its impacts. In this work, we designed novel magnesium oxide and graphene oxide (MgO@GO) composite free-standing membranes for nanofiltration. The membranes were characterized with the help of Fourier-transform infrared spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Further, free-standing MgO@GO composite membranes with different thicknesses were used to measure the water permeance. 410 nm-thick membranes showed high water permeance up to 480 ± 5 Lm−2 h−1bar−1. Further, the rejection efficiency of the membrane was measured against NaCl, CaCl2, Pb(NO3)2, CdCl2, and amoxicillin. The MgO@GO membrane (410 ± 10 nm) showed 100% rejection for amoxicillin and 99% for Pb(NO3)2, respectively. Additionally, the membranes were stable under acidic and neutral conditions for approximately ∼80 days and may used on an industrial scale to ensure water is clean and free from harmful substances.
AB - Environmental pollution significantly challenges human health, ecosystems, and the planet’s sustainability. Widespread air, water, and soil contamination from various pollutants requires effective and sustainable solutions to reduce or eliminate pollution and its impacts. In this work, we designed novel magnesium oxide and graphene oxide (MgO@GO) composite free-standing membranes for nanofiltration. The membranes were characterized with the help of Fourier-transform infrared spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Further, free-standing MgO@GO composite membranes with different thicknesses were used to measure the water permeance. 410 nm-thick membranes showed high water permeance up to 480 ± 5 Lm−2 h−1bar−1. Further, the rejection efficiency of the membrane was measured against NaCl, CaCl2, Pb(NO3)2, CdCl2, and amoxicillin. The MgO@GO membrane (410 ± 10 nm) showed 100% rejection for amoxicillin and 99% for Pb(NO3)2, respectively. Additionally, the membranes were stable under acidic and neutral conditions for approximately ∼80 days and may used on an industrial scale to ensure water is clean and free from harmful substances.
KW - Amoxicillin
KW - MgO@GO composite
KW - free-standing membrane
KW - heavy metal ions
KW - salts
UR - http://www.scopus.com/inward/record.url?scp=85178110090&partnerID=8YFLogxK
U2 - 10.1080/00032719.2023.2284841
DO - 10.1080/00032719.2023.2284841
M3 - Article
AN - SCOPUS:85178110090
SN - 0003-2719
VL - 57
SP - 2067
EP - 2084
JO - Analytical Letters
JF - Analytical Letters
IS - 13
ER -