TY - JOUR
T1 - Copper(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones
AU - West, Douglas X.
AU - Beraldo, Heloisa
AU - Nassar, Amal A.
AU - El-Saied, Fathy A.
AU - Ayad, Mohammed I.
PY - 1999
Y1 - 1999
N2 - Mononuclear and binuclear copper(II) complexes with four 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones have been prepared in EtOH solution and characterized by physical and spectral methods. I.r., electronic, and e.s.r. spectra of the complexes, as well as i.r., electronic, and n.m.r. spectra of the thiosemicarbazones, have been obtained. These thiosemicarbazones coordinate as anionic or neutral ligands via the thiosemicarbazone moiety's imine nitrogen and thiolate/ thione sulfur, the former on loss of the hydrazido hydrogen, N(2)H.
AB - Mononuclear and binuclear copper(II) complexes with four 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones have been prepared in EtOH solution and characterized by physical and spectral methods. I.r., electronic, and e.s.r. spectra of the complexes, as well as i.r., electronic, and n.m.r. spectra of the thiosemicarbazones, have been obtained. These thiosemicarbazones coordinate as anionic or neutral ligands via the thiosemicarbazone moiety's imine nitrogen and thiolate/ thione sulfur, the former on loss of the hydrazido hydrogen, N(2)H.
UR - http://www.scopus.com/inward/record.url?scp=0000372249&partnerID=8YFLogxK
U2 - 10.1023/A:1006967802158
DO - 10.1023/A:1006967802158
M3 - Article
AN - SCOPUS:0000372249
SN - 0340-4285
VL - 24
SP - 421
EP - 424
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 4
ER -