Towards synergy between spin-crossover and metal-ligand bond break in molecular crystals: Structural investigations of eight seven-coordinated Fe(II) macrocyclic complexes

Hongfeng Wang; Arnaud Grosjean; Chiara Sinito; Abdellah Kaiba; Chérif Baldé; Cédric Desplanches; Jean François Létard; Philippe Guionneau

doi:10.1039/c5ce00557d

Towards synergy between spin-crossover and metal-ligand bond break in molecular crystals: Structural investigations of eight seven-coordinated Fe(II) macrocyclic complexes

Hongfeng Wang
, Arnaud Grosjean
, Chiara Sinito
, Abdellah Kaiba
, Chérif Baldé
, Cédric Desplanches
, Jean François Létard
, Philippe Guionneau

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Sixteen structures of eight analogical Fe(II) macrocyclic complexes have been investigated exhibiting distinguishable structural properties even though no spin-crossover is observed. Notwithstanding, due to a synergistic effect between ligand field strength and intermolecular interaction, two of these complexes present very rare evidence for metal-ligand bond break at low temperature.

Original language	English
Pages (from-to)	4075-4079
Number of pages	5
Journal	CrystEngComm
Volume	17
Issue number	22
DOIs	https://doi.org/10.1039/c5ce00557d
State	Published - 14 Jun 2015
Externally published	Yes

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title = "Towards synergy between spin-crossover and metal-ligand bond break in molecular crystals: Structural investigations of eight seven-coordinated Fe(II) macrocyclic complexes",

abstract = "Sixteen structures of eight analogical Fe(II) macrocyclic complexes have been investigated exhibiting distinguishable structural properties even though no spin-crossover is observed. Notwithstanding, due to a synergistic effect between ligand field strength and intermolecular interaction, two of these complexes present very rare evidence for metal-ligand bond break at low temperature.",

author = "Hongfeng Wang and Arnaud Grosjean and Chiara Sinito and Abdellah Kaiba and Ch{\'e}rif Bald{\'e} and C{\'e}dric Desplanches and L{\'e}tard, \{Jean Fran{\c c}ois\} and Philippe Guionneau",

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doi = "10.1039/c5ce00557d",

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T1 - Towards synergy between spin-crossover and metal-ligand bond break in molecular crystals

T2 - Structural investigations of eight seven-coordinated Fe(II) macrocyclic complexes

AU - Wang, Hongfeng

AU - Grosjean, Arnaud

AU - Sinito, Chiara

AU - Kaiba, Abdellah

AU - Baldé, Chérif

AU - Desplanches, Cédric

AU - Létard, Jean François

AU - Guionneau, Philippe

PY - 2015/6/14

Y1 - 2015/6/14

N2 - Sixteen structures of eight analogical Fe(II) macrocyclic complexes have been investigated exhibiting distinguishable structural properties even though no spin-crossover is observed. Notwithstanding, due to a synergistic effect between ligand field strength and intermolecular interaction, two of these complexes present very rare evidence for metal-ligand bond break at low temperature.

AB - Sixteen structures of eight analogical Fe(II) macrocyclic complexes have been investigated exhibiting distinguishable structural properties even though no spin-crossover is observed. Notwithstanding, due to a synergistic effect between ligand field strength and intermolecular interaction, two of these complexes present very rare evidence for metal-ligand bond break at low temperature.

UR - https://www.scopus.com/pages/publications/84930216210

U2 - 10.1039/c5ce00557d

DO - 10.1039/c5ce00557d

M3 - Article

AN - SCOPUS:84930216210

SN - 1466-8033

VL - 17

SP - 4075

EP - 4079

JO - CrystEngComm

JF - CrystEngComm

IS - 22

ER -

Towards synergy between spin-crossover and metal-ligand bond break in molecular crystals: Structural investigations of eight seven-coordinated Fe(II) macrocyclic complexes

Abstract

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