The 1-D polymeric structure of the [Fe(NH2trz) 3](NO3)2·nH2O (with n = 2) spin crossover compound proven by single crystal investigations

Arnaud Grosjean; Nathalie Daro; Brice Kauffmann; Abdellah Kaiba; Jean Franois Létard; Philippe Guionneau

doi:10.1039/c1cc14220h

The 1-D polymeric structure of the [Fe(NH₂trz) ₃](NO₃)₂·nH₂O (with n = 2) spin crossover compound proven by single crystal investigations

Arnaud Grosjean, Nathalie Daro, Brice Kauffmann, Abdellah Kaiba, Jean Franois Létard, Philippe Guionneau

Research output: Contribution to journal › Article › peer-review

112 Scopus citations

Abstract

The first single crystal-based description of a spin transition compound from the patented [Fe(Rtrz)₃]X₂·nH₂O family is reported, properly the compound with Rtrz = 4-amino-1,2,4-triazole, X = NO₃ and n = 2. This study definitively proves the 1-D polymeric nature of the crystal structure and allows a description of the [Fe(Rtrz) ₃] chains, as well as of the anions and water implementation within the crystal lattice opening the possibility of subsequent investigations of the structure-property correlation within this peculiar family of spin transition compounds.

Original language	English
Pages (from-to)	12382-12384
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	45
DOIs	https://doi.org/10.1039/c1cc14220h
State	Published - 7 Dec 2011
Externally published	Yes

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abstract = "The first single crystal-based description of a spin transition compound from the patented [Fe(Rtrz)3]X2·nH2O family is reported, properly the compound with Rtrz = 4-amino-1,2,4-triazole, X = NO3 and n = 2. This study definitively proves the 1-D polymeric nature of the crystal structure and allows a description of the [Fe(Rtrz) 3] chains, as well as of the anions and water implementation within the crystal lattice opening the possibility of subsequent investigations of the structure-property correlation within this peculiar family of spin transition compounds.",

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T1 - The 1-D polymeric structure of the [Fe(NH2trz) 3](NO3)2·nH2O (with n = 2) spin crossover compound proven by single crystal investigations

AU - Grosjean, Arnaud

AU - Daro, Nathalie

AU - Kauffmann, Brice

AU - Kaiba, Abdellah

AU - Létard, Jean Franois

AU - Guionneau, Philippe

PY - 2011/12/7

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N2 - The first single crystal-based description of a spin transition compound from the patented [Fe(Rtrz)3]X2·nH2O family is reported, properly the compound with Rtrz = 4-amino-1,2,4-triazole, X = NO3 and n = 2. This study definitively proves the 1-D polymeric nature of the crystal structure and allows a description of the [Fe(Rtrz) 3] chains, as well as of the anions and water implementation within the crystal lattice opening the possibility of subsequent investigations of the structure-property correlation within this peculiar family of spin transition compounds.

AB - The first single crystal-based description of a spin transition compound from the patented [Fe(Rtrz)3]X2·nH2O family is reported, properly the compound with Rtrz = 4-amino-1,2,4-triazole, X = NO3 and n = 2. This study definitively proves the 1-D polymeric nature of the crystal structure and allows a description of the [Fe(Rtrz) 3] chains, as well as of the anions and water implementation within the crystal lattice opening the possibility of subsequent investigations of the structure-property correlation within this peculiar family of spin transition compounds.

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ER -

The 1-D polymeric structure of the [Fe(NH₂trz) ₃](NO₃)₂·nH₂O (with n = 2) spin crossover compound proven by single crystal investigations

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