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N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)-methylidene] adamantane-1-carbohydrazide sesquihydrate ethanol hemisolvate

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Abstract

In the asymmetric unit of the title compound, C19H 27ClN4O·0.5C2H6O·1. 5H2O, there are two mol-ecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH-N=CH- chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)° imidazolyl ring at the other end, three mol-ecules of water and one mol-ecule of ethanol. In both independent mol-ecules of the Schiff base, this chain displays an extended zigzag configuration. All their amino groups function as hydrogen-bond donors to water mol-ecules; these are linked to other acceptor atoms, generating a layer structure. O - H⋯O and O - H⋯N inter-actions involving the water mol-ecules also occur.

Original languageEnglish
Pages (from-to)o2131
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number8
DOIs
StatePublished - Aug 2010
Externally publishedYes

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