Mer-bis(2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthio-semicarbazonato-κ3S,N,O)cobalt(III) tetrafluoroborate

Jesús Valdés-Martínez; Simón Hernández-Ortega; Douglas X. West; Ayman K. El-Sawaf; Ramadan M. Ei-Bahanasawy; Fathy A. El-Saied

doi:10.1107/S1600536805022488

Mer-bis(2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthio-semicarbazonato-κ³S,N,O)cobalt(III) tetrafluoroborate

Jesús Valdés-Martínez, Simón Hernández-Ortega, Douglas X. West, Ayman K. El-Sawaf, Ramadan M. Ei-Bahanasawy, Fathy A. El-Saied

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3 Scopus citations

Abstract

In the title compound, [Co(C₁₅H₁₈N ₅OS)₂]BF₄, the cation has a distorted octahedral geometry around the Co^III atom, with two 2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthiosemicarbazonate anions coordinated as meridional tridentate ligands through the thiolate S, the antipyrine O and the imine N atoms. A tetrafluoroborate anion balances the charge of the Co^III complex.

Original language	English
Pages (from-to)	m1593-m1594
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	8
DOIs	https://doi.org/10.1107/S1600536805022488
State	Published - 1 Aug 2005
Externally published	Yes

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Valdés-Martínez, J., Hernández-Ortega, S., West, D. X., El-Sawaf, A. K., Ei-Bahanasawy, R. M., & El-Saied, F. A. (2005). Mer-bis(2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthio-semicarbazonato-κ³S,N,O)cobalt(III) tetrafluoroborate. Acta Crystallographica Section E: Structure Reports Online, 61(8), m1593-m1594. https://doi.org/10.1107/S1600536805022488

@article{6fb41acc956c4aab81def0c01d0e663a,

title = "Mer-bis(2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthio-semicarbazonato-κ3S,N,O)cobalt(III) tetrafluoroborate",

abstract = "In the title compound, [Co(C15H18N 5OS)2]BF4, the cation has a distorted octahedral geometry around the CoIII atom, with two 2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthiosemicarbazonate anions coordinated as meridional tridentate ligands through the thiolate S, the antipyrine O and the imine N atoms. A tetrafluoroborate anion balances the charge of the CoIII complex.",

author = "Jes{\'u}s Vald{\'e}s-Mart{\'i}nez and Sim{\'o}n Hern{\'a}ndez-Ortega and West, \{Douglas X.\} and El-Sawaf, \{Ayman K.\} and Ei-Bahanasawy, \{Ramadan M.\} and El-Saied, \{Fathy A.\}",

year = "2005",

month = aug,

day = "1",

doi = "10.1107/S1600536805022488",

language = "English",

volume = "61",

pages = "m1593--m1594",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

}

Valdés-Martínez, J, Hernández-Ortega, S, West, DX, El-Sawaf, AK, Ei-Bahanasawy, RM & El-Saied, FA 2005, 'Mer-bis(2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthio-semicarbazonato-κ³S,N,O)cobalt(III) tetrafluoroborate', Acta Crystallographica Section E: Structure Reports Online, vol. 61, no. 8, pp. m1593-m1594. https://doi.org/10.1107/S1600536805022488

Mer-bis(2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthio-semicarbazonato-κ³S,N,O)cobalt(III) tetrafluoroborate. / Valdés-Martínez, Jesús; Hernández-Ortega, Simón; West, Douglas X. et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 61, No. 8, 01.08.2005, p. m1593-m1594.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Mer-bis(2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthio-semicarbazonato-κ3S,N,O)cobalt(III) tetrafluoroborate

AU - Valdés-Martínez, Jesús

AU - Hernández-Ortega, Simón

AU - West, Douglas X.

AU - El-Sawaf, Ayman K.

AU - Ei-Bahanasawy, Ramadan M.

AU - El-Saied, Fathy A.

PY - 2005/8/1

Y1 - 2005/8/1

N2 - In the title compound, [Co(C15H18N 5OS)2]BF4, the cation has a distorted octahedral geometry around the CoIII atom, with two 2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthiosemicarbazonate anions coordinated as meridional tridentate ligands through the thiolate S, the antipyrine O and the imine N atoms. A tetrafluoroborate anion balances the charge of the CoIII complex.

AB - In the title compound, [Co(C15H18N 5OS)2]BF4, the cation has a distorted octahedral geometry around the CoIII atom, with two 2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthiosemicarbazonate anions coordinated as meridional tridentate ligands through the thiolate S, the antipyrine O and the imine N atoms. A tetrafluoroborate anion balances the charge of the CoIII complex.

UR - http://www.scopus.com/inward/record.url?scp=32244434338&partnerID=8YFLogxK

U2 - 10.1107/S1600536805022488

DO - 10.1107/S1600536805022488

M3 - Article

AN - SCOPUS:32244434338

SN - 1600-5368

VL - 61

SP - m1593-m1594

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Mer-bis(2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthio-semicarbazonato-κ³S,N,O)cobalt(III) tetrafluoroborate

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