TY - JOUR
T1 - (E)-2-[1-(1-Benzothio-phen-3-yl)ethyl-idene]hydrazinecarbothio-amide methanol hemisolvate
AU - Kayed, Safaa Fares
AU - Farina, Yang
AU - Kassim, Mohammad
AU - Simpson, Jim
PY - 2008
Y1 - 2008
N2 - The asymmetric unit of the title compound, C11H11N3S2·0.5CH4O, contains four thio-semicarbazone mol-ecules and two methanol solvent mol-ecules. Each hydrazinecarbothio-amide mol-ecule adopts an E configuration with respect to the C=N double bond and is stabilized by an intra-molecular N - H⋯N hydrogen bond, resulting in an S(5) ring motif. In the crystal structure, an extensive network of N - H⋯O, N - H⋯N, O - H⋯S and N - H⋯S hydrogen bonds and weak C - H⋯O, C - H⋯N and C - H⋯S contacts together with an S⋯S [3.5958 (14) Å] and a C - H⋯π inter-action form a three-dimensional network.
AB - The asymmetric unit of the title compound, C11H11N3S2·0.5CH4O, contains four thio-semicarbazone mol-ecules and two methanol solvent mol-ecules. Each hydrazinecarbothio-amide mol-ecule adopts an E configuration with respect to the C=N double bond and is stabilized by an intra-molecular N - H⋯N hydrogen bond, resulting in an S(5) ring motif. In the crystal structure, an extensive network of N - H⋯O, N - H⋯N, O - H⋯S and N - H⋯S hydrogen bonds and weak C - H⋯O, C - H⋯N and C - H⋯S contacts together with an S⋯S [3.5958 (14) Å] and a C - H⋯π inter-action form a three-dimensional network.
UR - http://www.scopus.com/inward/record.url?scp=57349188497&partnerID=8YFLogxK
U2 - 10.1107/S160053680801297X
DO - 10.1107/S160053680801297X
M3 - Article
AN - SCOPUS:57349188497
SN - 1600-5368
VL - 64
SP - o1022
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 6
ER -