Crystal structure of a new silver(I) coordination polymer assembled from imidazolidine-2-thione (Imt), {[Ag2(Imt)3](NO3)2}n

Saeed Ahmad; Seerat-Ur-Rehman; Muhammad Nadeem Arshad; Abdullah M. Asiri; Tobias Rüffer; Muhammad Aziz Choudhary; Anvarhusein A. Isab

doi:10.1515/znb-2019-0065

Crystal structure of a new silver(I) coordination polymer assembled from imidazolidine-2-thione (Imt), {[Ag₂(Imt)₃](NO₃)₂}_n

Saeed Ahmad
, Seerat-Ur-Rehman
, Muhammad Nadeem Arshad
, Abdullah M. Asiri
, Tobias Rüffer
, Muhammad Aziz Choudhary
, Anvarhusein A. Isab

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A new polymeric silver(I) complex of imidazolidine-2-thione (Imt), {[Ag₂(Imt)₃](NO₃)₂}_n (1) was prepared and its structure was determined by single-crystal X-ray diffraction analysis. The silver atoms form infinite chains with two Ag - S(Imt) - Ag strands linked to each other by sulfur atoms of μ₄-Imt ligands. Each silver(I) ion is bound to four sulfur atoms of bridging Imt ligands in a distorted tetrahedral environment. The crystal structure is stabilized by hydrogen bonding and weak argentophilic interactions. The hydrogen bonded nitrate ions connect the 1D chains to generate a 2D layer structure.

Original language	English
Pages (from-to)	565-569
Number of pages	5
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	74
Issue number	7-8
DOIs	https://doi.org/10.1515/znb-2019-0065
State	Published - 27 Aug 2019
Externally published	Yes

Keywords

2D polymer
crystal structure
imidazolidine-2-thione
nitrate
silver(I)

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10.1515/znb-2019-0065

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title = "Crystal structure of a new silver(I) coordination polymer assembled from imidazolidine-2-thione (Imt), \{[Ag2(Imt)3](NO3)2\}n",

abstract = "A new polymeric silver(I) complex of imidazolidine-2-thione (Imt), \{[Ag2(Imt)3](NO3)2\}n (1) was prepared and its structure was determined by single-crystal X-ray diffraction analysis. The silver atoms form infinite chains with two Ag - S(Imt) - Ag strands linked to each other by sulfur atoms of μ4-Imt ligands. Each silver(I) ion is bound to four sulfur atoms of bridging Imt ligands in a distorted tetrahedral environment. The crystal structure is stabilized by hydrogen bonding and weak argentophilic interactions. The hydrogen bonded nitrate ions connect the 1D chains to generate a 2D layer structure.",

keywords = "2D polymer, crystal structure, imidazolidine-2-thione, nitrate, silver(I)",

author = "Saeed Ahmad and Seerat-Ur-Rehman and Arshad, \{Muhammad Nadeem\} and Asiri, \{Abdullah M.\} and Tobias R{\"u}ffer and Choudhary, \{Muhammad Aziz\} and Isab, \{Anvarhusein A.\}",

note = "Publisher Copyright: {\textcopyright} 2019 Walter de Gruyter GmbH, Berlin/Boston.",

year = "2019",

month = aug,

day = "27",

doi = "10.1515/znb-2019-0065",

language = "English",

volume = "74",

pages = "565--569",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "7-8",

}

Crystal structure of a new silver(I) coordination polymer assembled from imidazolidine-2-thione (Imt), {[Ag₂(Imt)₃](NO₃)₂}_n. / Ahmad, Saeed; Seerat-Ur-Rehman; Arshad, Muhammad Nadeem et al.
In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 74, No. 7-8, 27.08.2019, p. 565-569.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal structure of a new silver(I) coordination polymer assembled from imidazolidine-2-thione (Imt), {[Ag2(Imt)3](NO3)2}n

AU - Ahmad, Saeed

AU - Seerat-Ur-Rehman,

AU - Arshad, Muhammad Nadeem

AU - Asiri, Abdullah M.

AU - Rüffer, Tobias

AU - Choudhary, Muhammad Aziz

AU - Isab, Anvarhusein A.

PY - 2019/8/27

Y1 - 2019/8/27

N2 - A new polymeric silver(I) complex of imidazolidine-2-thione (Imt), {[Ag2(Imt)3](NO3)2}n (1) was prepared and its structure was determined by single-crystal X-ray diffraction analysis. The silver atoms form infinite chains with two Ag - S(Imt) - Ag strands linked to each other by sulfur atoms of μ4-Imt ligands. Each silver(I) ion is bound to four sulfur atoms of bridging Imt ligands in a distorted tetrahedral environment. The crystal structure is stabilized by hydrogen bonding and weak argentophilic interactions. The hydrogen bonded nitrate ions connect the 1D chains to generate a 2D layer structure.

AB - A new polymeric silver(I) complex of imidazolidine-2-thione (Imt), {[Ag2(Imt)3](NO3)2}n (1) was prepared and its structure was determined by single-crystal X-ray diffraction analysis. The silver atoms form infinite chains with two Ag - S(Imt) - Ag strands linked to each other by sulfur atoms of μ4-Imt ligands. Each silver(I) ion is bound to four sulfur atoms of bridging Imt ligands in a distorted tetrahedral environment. The crystal structure is stabilized by hydrogen bonding and weak argentophilic interactions. The hydrogen bonded nitrate ions connect the 1D chains to generate a 2D layer structure.

KW - 2D polymer

KW - crystal structure

KW - imidazolidine-2-thione

KW - nitrate

KW - silver(I)

UR - https://www.scopus.com/pages/publications/85069736307

U2 - 10.1515/znb-2019-0065

DO - 10.1515/znb-2019-0065

M3 - Article

AN - SCOPUS:85069736307

SN - 0932-0776

VL - 74

SP - 565

EP - 569

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 7-8

ER -

Crystal structure of a new silver(I) coordination polymer assembled from imidazolidine-2-thione (Imt), {[Ag₂(Imt)₃](NO₃)₂}_n

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