Complexation of 2,6-bis(3-pyrazolyl)pyridine-bis(thiocyanato)iron(II) with a bridging 4,4′-bipyridine: A new example of a dinuclear spin crossover complex

Dalila Fedaoui, Yacine Bouhadja, Abdellah Kaiba, Philippe Guionneau, Jean François Létard, Patrick Rosa

Research output: Contribution to journalArticlepeer-review

44 Scopus citations

Abstract

Investigation of the coordination behavior of 2,6-bis(3-pyrazolyl) pyridine-bis(thiocyanato)iron(II) towards bridging ligands led to the discovery of a novel dinuclear complex showing spin-crossover. Chemical and structural characterization and a first report of physical properties are presented.

Original languageEnglish
Pages (from-to)1022-1026
Number of pages5
JournalEuropean Journal of Inorganic Chemistry
Issue number7
DOIs
StatePublished - Mar 2008
Externally publishedYes

Keywords

  • Dinuclear complexes
  • Iron
  • Magnetic properties
  • Spin crossover

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