TY - JOUR
T1 - Adsorptive Removal of Boron by DIAION™ CRB05
T2 - Characterization, Kinetics, Isotherm, and Optimization by Response Surface Methodology
AU - Al-dhawi, Baker Nasser Saleh
AU - Kutty, Shamsul Rahman Mohamed
AU - Hayder, Gasim
AU - Elnaim, Bushra Mohamed Elamin
AU - Mnzool, Mohammed
AU - Noor, Azmatullah
AU - Saeed, Anwar Ameen Hezam
AU - Al-Mahbashi, Najib Mohammed Yahya
AU - Al-Nini, Ahmed
AU - Jagaba, Ahmad Hussaini
N1 - Publisher Copyright:
© 2023 by the authors.
PY - 2023/2
Y1 - 2023/2
N2 - A significant issue for the ecosystem is the presence of boron in water resources, particularly in produced water. Batch and dynamic experiments were used in this research to extract boron in the form of boric acid from aqueous solutions using boron selective resins, DIAION CRB05. DIAION™ CRB05 is an adsorbent that is effective in extracting boron from aqueous solutions due to its high binding capacity and selectivity for boron ions, and it is also regenerable, making it cost-effective and sustainable. Field Emission Scanning Electron Microscopy (FESEM), X-ray diffraction (XRD), and FTIR analysis for DIAION CRB05 characterization. To increase the adsorption capacity and find the ideal values for predictor variables such as pH, adsorbent dose, time, and boric acid concentration, the Box–Behnken response surface method (RSM) was applied. The dosage was reported to be 2000 mg/L at pH 2 and boron initial concentration of 1115 mg/L with 255 min for the highest removal anticipated from RSM. According to the outcomes of this research, the DIAION CRB05 material enhanced boron removal capability and has superior performance to several currently available adsorbents, which makes it suitable for use as an adsorbent for removing boric acid from aqueous solutions. The outcomes of isotherm and kinetic experiments were fitted using linear methods. The Temkin isotherm and the pseudo-first-order model were found to have good fits after comparison with R2 of 0.998, and 0.997, respectively. The results of the study demonstrate the effectiveness of DIAION™ CRB05 in removing boron from aqueous solutions and provide insight into the optimal conditions for the adsorption process. Thus, the DIAION CRB05 resin was chosen as the ideal choice for recovering boron from an aqueous solution because of its higher sorption capacity and percentage of boron absorbed.
AB - A significant issue for the ecosystem is the presence of boron in water resources, particularly in produced water. Batch and dynamic experiments were used in this research to extract boron in the form of boric acid from aqueous solutions using boron selective resins, DIAION CRB05. DIAION™ CRB05 is an adsorbent that is effective in extracting boron from aqueous solutions due to its high binding capacity and selectivity for boron ions, and it is also regenerable, making it cost-effective and sustainable. Field Emission Scanning Electron Microscopy (FESEM), X-ray diffraction (XRD), and FTIR analysis for DIAION CRB05 characterization. To increase the adsorption capacity and find the ideal values for predictor variables such as pH, adsorbent dose, time, and boric acid concentration, the Box–Behnken response surface method (RSM) was applied. The dosage was reported to be 2000 mg/L at pH 2 and boron initial concentration of 1115 mg/L with 255 min for the highest removal anticipated from RSM. According to the outcomes of this research, the DIAION CRB05 material enhanced boron removal capability and has superior performance to several currently available adsorbents, which makes it suitable for use as an adsorbent for removing boric acid from aqueous solutions. The outcomes of isotherm and kinetic experiments were fitted using linear methods. The Temkin isotherm and the pseudo-first-order model were found to have good fits after comparison with R2 of 0.998, and 0.997, respectively. The results of the study demonstrate the effectiveness of DIAION™ CRB05 in removing boron from aqueous solutions and provide insight into the optimal conditions for the adsorption process. Thus, the DIAION CRB05 resin was chosen as the ideal choice for recovering boron from an aqueous solution because of its higher sorption capacity and percentage of boron absorbed.
KW - DIAION CRB05 resin
KW - adsorption
KW - boron
KW - kinetic studies
KW - response surface methodology
UR - https://www.scopus.com/pages/publications/85149216995
U2 - 10.3390/pr11020453
DO - 10.3390/pr11020453
M3 - Article
AN - SCOPUS:85149216995
SN - 2227-9717
VL - 11
JO - Processes
JF - Processes
IS - 2
M1 - 453
ER -