A reversible metal-ligand bond break associated to a spin-crossover

Philippe Guionneau; Frédéric Le Gac; Abdellah Kaiba; José Sánchez Costa; Daniel Chasseau; Jean François Létard

doi:10.1039/b707836f

A reversible metal-ligand bond break associated to a spin-crossover

Philippe Guionneau
, Frédéric Le Gac
, Abdellah Kaiba
, José Sánchez Costa
, Daniel Chasseau
, Jean François Létard

Université Bordeaux 1

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

The [Fe^IIL(CN)₂]·H₂O complex, dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2, 12,14,16-pentaene]iron(ii) monohydrate, exhibits a thermal induced metal-ligand bond break reversible in the solid state and associated to a spin crossover that corresponds to an unprecedented structurally characterized modification of the coordination metal environment from a hepta-coordinate high spin state to a hexa-coordinate low spin state.

Original language	English
Pages (from-to)	3723-3725
Number of pages	3
Journal	Chemical Communications
Issue number	36
DOIs	https://doi.org/10.1039/b707836f
State	Published - 2007
Externally published	Yes

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@article{e4d0bfd6229e4b52ad2384e9892bf99d,

title = "A reversible metal-ligand bond break associated to a spin-crossover",

abstract = "The [FeIIL(CN)2]·H2O complex, dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2, 12,14,16-pentaene]iron(ii) monohydrate, exhibits a thermal induced metal-ligand bond break reversible in the solid state and associated to a spin crossover that corresponds to an unprecedented structurally characterized modification of the coordination metal environment from a hepta-coordinate high spin state to a hexa-coordinate low spin state.",

author = "Philippe Guionneau and \{Le Gac\}, Fr{\'e}d{\'e}ric and Abdellah Kaiba and Costa, \{Jos{\'e} S{\'a}nchez\} and Daniel Chasseau and L{\'e}tard, \{Jean Fran{\c c}ois\}",

year = "2007",

doi = "10.1039/b707836f",

language = "English",

pages = "3723--3725",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "36",

}

TY - JOUR

T1 - A reversible metal-ligand bond break associated to a spin-crossover

AU - Guionneau, Philippe

AU - Le Gac, Frédéric

AU - Kaiba, Abdellah

AU - Costa, José Sánchez

AU - Chasseau, Daniel

AU - Létard, Jean François

PY - 2007

Y1 - 2007

N2 - The [FeIIL(CN)2]·H2O complex, dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2, 12,14,16-pentaene]iron(ii) monohydrate, exhibits a thermal induced metal-ligand bond break reversible in the solid state and associated to a spin crossover that corresponds to an unprecedented structurally characterized modification of the coordination metal environment from a hepta-coordinate high spin state to a hexa-coordinate low spin state.

AB - The [FeIIL(CN)2]·H2O complex, dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2, 12,14,16-pentaene]iron(ii) monohydrate, exhibits a thermal induced metal-ligand bond break reversible in the solid state and associated to a spin crossover that corresponds to an unprecedented structurally characterized modification of the coordination metal environment from a hepta-coordinate high spin state to a hexa-coordinate low spin state.

UR - https://www.scopus.com/pages/publications/34548625152

U2 - 10.1039/b707836f

DO - 10.1039/b707836f

M3 - Article

AN - SCOPUS:34548625152

SN - 1359-7345

SP - 3723

EP - 3725

JO - Chemical Communications

JF - Chemical Communications

IS - 36

ER -

A reversible metal-ligand bond break associated to a spin-crossover

Abstract

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