TY - JOUR
T1 - 3-(Adamantan-1-yl)-4-[(E)-(2,6-difluorobenzylidene)amino] -1-[(4-ethylpiperazin-1-yl)methyl]-4,5-dihydro-1H-1,2,4-triazole-5-thione
AU - Al-Tamimi, Abdul Malek S.
AU - Al-Abdullah, Ebtehal S.
AU - El-Emam, Ali A.
AU - Ng, Seik Weng
AU - Tiekink, Edward R.T.
PY - 2013/5
Y1 - 2013/5
N2 - In the title compound, C26H34F2N 6S, the triazole ring is linked to a benzene ring via an imine bond [N=C = 1.255 (2) Å; conformation: E], with a dihedral angle of 25.21 (11)° between the rings. The 4-ethylpiperazinyl residue is folded away from the thione-S atom. In the crystal, helical supramolecular chains propagating along [010] and sustained by weak C - S⋯π(triazole) interactions occur [S⋯centroid distance = 3.2872 (10) Å]. Links between these chains are of the type benzene-C - H⋯N(imine) and π-π [between centrosymmetrically related benzene rings with an inter-centroid distance of 3.9241 (15) Å] and result in a three-dimensional architecture.
AB - In the title compound, C26H34F2N 6S, the triazole ring is linked to a benzene ring via an imine bond [N=C = 1.255 (2) Å; conformation: E], with a dihedral angle of 25.21 (11)° between the rings. The 4-ethylpiperazinyl residue is folded away from the thione-S atom. In the crystal, helical supramolecular chains propagating along [010] and sustained by weak C - S⋯π(triazole) interactions occur [S⋯centroid distance = 3.2872 (10) Å]. Links between these chains are of the type benzene-C - H⋯N(imine) and π-π [between centrosymmetrically related benzene rings with an inter-centroid distance of 3.9241 (15) Å] and result in a three-dimensional architecture.
UR - https://www.scopus.com/pages/publications/84877308792
U2 - 10.1107/S1600536813009264
DO - 10.1107/S1600536813009264
M3 - Article
AN - SCOPUS:84877308792
SN - 1600-5368
VL - 69
SP - o685-o686
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 5
ER -